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• W2023235929 abstract "We show that a simple model consisting of a binary hard-sphere mixture in a narrow cylindrical pore can lead to strong size selectivity by considering a situation where each species of the mixture sees a different radius of the cylinder. Two mechanisms are proposed to explain the observed results depending on the radius of the cylinder: for large radii the selectivity is driven by an enhancement of the depletion forces at the cylinder walls whereas for the narrowest cylinders excluded-volume effects lead to a shift of the effective chemical potential of the particles in the pore." @default.
• W2023235929 created "2016-06-24" @default.
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• W2023235929 date "2011-10-21" @default.
• W2023235929 modified "2023-10-16" @default.
• W2023235929 title "Entropic selectivity of binary mixtures in cylindrical pores" @default.
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• W2023235929 doi "https://doi.org/10.1063/1.3643117" @default.
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