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- W2023243933 abstract "Abstract The crystal structure of the title compound (C3H12N2)2Cu2Br6, is monoclinic, space group P21/n, with lattice constants a=8.222(2), b=11.214(2), c=10.646(2) A, β=91.97(1)° and V=981.0(3) A3. The structure contains anionic Cu2Br62− dimers and N-methylethylenediammonium (henceforth MEDA2+) cations. The centrosymmetric dimer units are composed of two edge-shared CuBr4 tetrahedra, with bridging Cu–Br distances 0.08 A longer than the terminal distances. A pair of MEDA2+ cations hydrogen bond to each dimer via two of the –NH3+ hydrogen atoms and one of the –NH2+- hydrogen atoms. Additional hydrogen bonding between the cations and anions tie the structure together in a complex supramolecular network." @default.
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- W2023243933 date "2004-03-01" @default.
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- W2023243933 title "Crystal structure of bis(N-methylethylenediammonium) hexabromodicuprate(I)" @default.
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