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- W2023244033 abstract "Dielectric properties of compact discs of α-zirconium phosphate, α-zirconium bis(hydroxymethanephosphonate), in an- hydrous and monohydrated form, and of α-zirconium bis(carboxymethanephosphonate) were investigated, as a function of the temperature, at frequencies ranging from 30 Hz to 100 kHz and, in some cases, up to 2.5 MHz. In all the compounds a low frequency dispersion has been found and ascribed to polarization phenomena due to charge transfer through the compact discs. The comparison of the ϵ∞ values of α-Zr(HOOCCH2PO3)2, α-Zr(HPO4)2· H2O and α-Zr(HOCH2PO3)2· H2O with that of α-zirconium pyrophosphate clearly indicate that orientation polarization is not present in these compounds. The dehydration of α-Zr(HPO4)2·H2O and of α-Zr(HOCH2PO3)2· H2O is associated with an increment, at low frequency, of the real component of the dielectric constant and with a high frequency dispersion, due to relaxation of orientation polarization. Dielectric properties of α-zirconium phosphate are discussed on the ground of its crystalline structure." @default.
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- W2023244033 date "1983-02-01" @default.
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- W2023244033 title "Dielectric properties of α-zirconium phosphate and its organic derivatives☆" @default.
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- W2023244033 doi "https://doi.org/10.1016/0167-2738(83)90036-x" @default.
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