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- W2023246095 abstract "The vibrational spectra of 1,5-cyclooctadiene (C8H12, COD) and the rhodium(I) and copper(I) complexes, [(COD)RhCl]2, [(COD)CuCl]2 and (COD)2CuClO4, have been investigated. In the liquid state, COD exists in a C2ν ‘tub’ configuration; the same structure is apparently also preserved in the solid at −196°C. The spectra of the dimeric complexes are in accord with the known D2h molecular symmetries and assignments for the ν(CC), ν(MCl) and ν(M—olefin) vibrations are proposed accordingly. The spectra of (COD)2CuClO4 indicate the presence of a non-bonded olefinic group and a three-coordinate structure is proposed for the (COD)2Cu+ ion." @default.
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- W2023246095 title "Vibrational spectra of 1,5-cyclooctadiene, di-μ-chlorobis[(1,5-cyclooctadiene)rhodium(I)], di-μ-chlorobis[(1,5-cyclooctadiene)copper(I)] and bis(1,5-cyclooctadiene)copper(I) perchlorate" @default.
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- W2023246095 doi "https://doi.org/10.1002/jrs.1250070312" @default.
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