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- W2023246369 abstract "Die kontrollierte Zersetzung der arsenverbruckten Dreikernkomplexe (CO)4M[As(CH3)2 M′(CO)3C5H5]2 (1) (M, M′ Cr, Mo, W) fuhrt zu den Zweikernkomplexen (CO)5M[μ-As(CH3)2]M′(CO)2C5H5(M M′) (2) und/oder (CO)5M As(CH3)2 M′(CO)3C5H5 (3) mit und ohne Metall-Metall-Bindung. Die Reaktivitat der Metall-Metall-Bindungen in 2 zeigt sich in ihrer Spaltung mit Nucleophilen und in einer katalytischen Polymerisation des Norbornadiens.Organometallic Lewis Bases, XXXVII: Preparation and Reactions of the Metal-Metal Bonded Dinuclear Complexes (CO)5M[μ-As(CH3)2]M′(CO)2 C5H5 (M, M′ Cr, Mo, W)The controlled decomposition of the arsenic bridged trinuclear complexes (CO)4M[As(CH3)2 M′(CO)3C5H5]2 (1) (M, M′ Cr, Mo, W) leads to the dinuclear complexes (CO)5M[μ-As(CH3)2]M′(CO)2C5H5(M M′) (2) and/or (CO)5M As(CH3)2 M′(CO)3C5H5 (3) with and without metal-metal bonds. The reactivity of the metal-metal bonds in 2 is shown by their cleavage with nucleophiles and by a catalytic polymerization of norbornadiene." @default.
- W2023246369 created "2016-06-24" @default.
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- W2023246369 date "1978-06-01" @default.
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- W2023246369 title "Metallorganische Lewis-Basen, XXXVII: Darstellung und Reaktionen der Metall-Metall-verknüpften Zweikernkomplexe (CO)5M[μ-As(CH3)2]M′(CO)2C2H5 (M, M′ Cr, Mo, W)" @default.
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- W2023246369 doi "https://doi.org/10.1002/cber.19781110615" @default.
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