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- W2023249155 abstract "In compounds of the type Ph3SbY2 and (Ph3Sb-O-SbPh3Y2 the C(Ph)-Sb asymmetric stretching frequency occurs between 471 and 445 cm-2. Absorption due to Sb-O-Sb occurs near 750 cm-2. In triphenylantimony dinitrate the nitrate group is considerably more covalent than in trimethylantimony dinitrate. The spectral results with compounds of the type Ph3SbY2 are consistent with a trigonal bipyramidal molecule. X-ray diffraction studies by previous workers have clearly demonstrated such a structure for only Ph3SbCl2. Oxybis(triphenylantimony) diperchlorate appears to contain a perchlorate ion. The other compounds of the type (Ph3Sb-O-SbPh3)Y2 which we have studied appear to be covalent and probably consist of two trigonal bipyramidal Ph3SbY groups sharing an apical oxygen atom." @default.
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- W2023249155 date "1965-07-01" @default.
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- W2023249155 title "The infrared spectra of some phenyl-substituted pentavalent antimony compounds" @default.
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- W2023249155 doi "https://doi.org/10.1016/s0022-328x(00)82370-0" @default.
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