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- W2023249199 abstract "The relationship between the tail architecture and performance of hybrid AOT analogue surfactants has been investigated. Three hybrid surfactants were synthesised using hydrocarbon CO2-philic tails with different levels of chain branching. The performance of each surfactant was investigated via high-pressure phase behaviour, UV-visible spectroscopy, and air–water (a/w) surface tension measurements. Notably, the incorporation of hydrocarbon CO2-philic tails with a high degree of branching has been found to significantly boost CO2-philicity, allowing the surfactant to stabilise water-in-CO2 (w/c) microemulsions at low cloud pressures, Ptrans. The newly synthesised hybrid CF2/SIS1 (sodium (4H, 4H, 5H, 5H, 5H-pentafluoropenyl-5,7,7-trimethyl-2-(1,3,3-trimethyl-buthyl)-octyl)-2-sulfosuccinate) is a CO2-philic surfactant that contains the lowest amount of fluorine (15.01 wt%) and exhibits the highest efficiency of any di-chain surfactant to date. High-pressure phase behaviour studies provided a maximum water-to-surfactant molar ratio (wmax) of wmax = 39, which is usually only observed from surfactants with long fluorocarbon chains. The present results are beneficial for expanding the pool of economical, effective, and efficient surfactants available for CO2-based technology." @default.
- W2023249199 created "2016-06-24" @default.
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- W2023249199 date "2015-03-01" @default.
- W2023249199 modified "2023-10-07" @default.
- W2023249199 title "Economical and Efficient Hybrid Surfactant with Low Fluorine Content for the Stabilisation of Water-in-CO2 Microemulsions" @default.
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- W2023249199 doi "https://doi.org/10.1016/j.supflu.2015.01.012" @default.
- W2023249199 hasPublicationYear "2015" @default.
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