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- W2023251041 abstract "The β(1→4) glycosidic linkage found in lactose is a prevalent structural motif in many carbohydrates and glycoconjugates. Using UV and IR ion-dip spectroscopies to probe benzyl lactoside isolated in the gas phase, we find that the disaccharide unit adopts only a single, rigid structure. Its fully resolved infrared ion-dip spectrum is in excellent agreement with that of the global minimum structure computed ab initio. This has glycosidic torsion angles of φH (H1−C1−O−C4‘) ≈ 180° and ψH (C1−O−C4‘−H4‘) ≈ 0° which correspond to a rotation of ∼150° about the glycosidic bond compared to the accepted solution-phase conformation. We discuss the biological implications of this discovery and the generality of the strategies employed in making it." @default.
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- W2023251041 date "2004-04-09" @default.
- W2023251041 modified "2023-10-16" @default.
- W2023251041 title "Probing the Glycosidic Linkage: UV and IR Ion-Dip Spectroscopy of a Lactoside" @default.
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- W2023251041 doi "https://doi.org/10.1021/ja031679k" @default.
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