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- W2023251296 abstract "The reaction mechanism of the LiH addition to α-chiral ketones and acylsilanes was calculated at the ab initio MP2/6-311+G**//RHF/6-31G* level. The selectivities predicted on the basis of the computed transition states and reaction barriers compare well with the experimental data. For compounds possessing very large groups, anti-Cram selectivity was found; silicon-containing compounds should show the same types of selectivity as their carbon analogs. The calculations suggest that a revision of the Felkin−Anh model is necessary and a proposal for such a revision is given. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)" @default.
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- W2023251296 date "2002-08-01" @default.
- W2023251296 modified "2023-10-01" @default.
- W2023251296 title "The Cram Rule Revisited Once More — Revision of the Felkin−Anh Model" @default.
- W2023251296 doi "https://doi.org/10.1002/1099-0690(200208)2002:16<2770::aid-ejoc2770>3.0.co;2-x" @default.
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