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- W2023251636 abstract "1. An extracellular, chlorosis-inducing agent and several related, but inactive, products of a Pseudomonas sp. attacking timothy (Phleum pratense L.) were prepared by chromatographic means. 2. The chlorosis-inducing agent was identified by spectroscopic and chromatographic methods and shown to be a mixture of two dipeptides, which contain a tabtoxinine-β-lactam residue linked to the amino group of either threonine or serine. These compounds are identical to those previously described from Pseudomonas tabaci. 3. Inactive isomers of the above dipeptides were also characterized. These products contained a tabtoxinine-δ-lactam residue linked to the amino group of either threonine or serine. 4. The last product, a previously unidentified amino acid, was characterized as tabtoxinine-δ-lactam or 3-aminomethyl-6-aminomethyl-6-carboxyl-3-hydroxy-2-piperidone. 5. The amino acid tabtoxinine (5-amino-2-aminomethyl-2-hydroxyapidic acid) was isolated from acid hydrolysates of the above natural products. It was partially converted to tabtoxinine-δ-lactam by heating at 100°C for the 60 min at pH 3.1. 6. The trivial name tabtoxin is proposed for the threonine-containing, chlorosis-inducing dipeptide. The less abundant analog would be designated [2-serine]-tabtoxin. Similarly, the inactive isomers would be designated isotabtoxin and [2-serine]-isotabtoxin. 7. Using mass spectrometry the structure of tabtoxin as proposed by W.W. Stewart (Nature, 229 (1971) 172) was confirmed." @default.
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- W2023251636 date "1972-11-01" @default.
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- W2023251636 title "Characterization of chlorosis-inducing toxins from a plant pathogenic pseudomonas SP" @default.
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- W2023251636 doi "https://doi.org/10.1016/0304-4165(72)90096-7" @default.
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