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- W2023253019 abstract "The physical properties (electrical absorptions, bandgaps, electroconductivities) of a completely regioregular head-to-tail polyalkylthiophene and a totally regiorandom isopolymer are reported. The regioregular polyalkylthiophenes exhibit, to date, the smallest bandgap (1.7 eV) and the highest intrinsic conductivity (10−6 S/cm for undoped polymer) of polyalkylthiophenes. The bandgap is 0.3–0.5 eV lower than that of normal polyalkylthiophenes (2.0–2.2 eV) and the intrinsic conductivity is three orders of magnitude higher than that of normal polyalkylthiophenes (10−9–10−10 S/cm). The regioregular polymer also exhibits a large iodine-doped conductivity (average 1350 S/cm) of polymer film. A bipolaron gap state is generated in the iodine-doped regioregular polyalkylthiophene film by chemical oxidation, while it fails for the regiorandom polyalkylthiophene." @default.
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- W2023253019 date "1993-09-01" @default.
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- W2023253019 title "Polyalkylthiophenes with the smallest bandgap and the highest intrinsic conductivity" @default.
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- W2023253019 doi "https://doi.org/10.1016/0379-6779(93)91240-3" @default.
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