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- W2023256405 abstract "In this paper, graphene-modified Li3V2(PO4)3 composites have been developed as Li-ion battery cathode materials with high specific capacity and excellent cycling stability. The composites are prepared by spray–drying process using graphene oxide nanosheet and citric acid as carbon source. X-ray diffraction patterns demonstrate that the as-prepared samples are well crystallized with orderly monoclinic structures. SEM and TEM images reveal that the 3D network graphene and Li3V2(PO4)3 primary nanoparticles interlace with each other. The citric acid-derived amorphous carbon species interrupt the stacking of graphene sheets and minimize in-plane anisotropy of electronic migration within graphene layers, which would facilitate fast electron migration and Li+ diffusion throughout the micro-sized spherical secondary particles. The discharge capacity of the composite could respectively achieve 131.4 and 181.5 mAh g−1 in the voltage range 3.0–4.3 V and 3.0–4.8 V at 0.1C discharge rate, which almost reach the theoretical capacity of the cathode material. Both of them nearly showed no capacity decay at 0.1C charging and discharging rate after long cycles." @default.
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- W2023256405 date "2012-12-01" @default.
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- W2023256405 title "Graphene modified Li3V2(PO4)3 as a high-performance cathode material for lithium ion batteries" @default.
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- W2023256405 doi "https://doi.org/10.1016/j.electacta.2012.08.067" @default.
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