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• W2023257716 abstract "2,6-Bis(chloromethyl)pyridine was oxidatively added to [IrCl(PPh3)3] to give cis(P,P)-[IrCl2(ClCH2-py-CH2-C,N)(PPh3)2] (ClCH2-py-CH2 = {2-(6-chloromethyl)pyridyl}methyl) (1a), of which the cycloiridated structure has been established by an X-ray analysis. Complex 1a further reacts with [RhCl(PPh3)3] to afford an Ir(III)–Rh(III) complex [IrRhCl2(μ-Cl)2(μ-CH2-py-CH2-C,N,C′)(PPh3)3](CH2-py-CH2 = 2,6-dimethylpyridine-α,α′-diyl) (3). Upon prolonged heating in toluene, 3 liberates one triphenylphosphine ligand and [IrRhCl2(μ-Cl)2(μ-CH2-py-CH2-C,N,C′)(PPh3)2] (4) is formed. X-Ray crystal structure determinations of 3 and 4 have revealed their dinuclear structures, in which the metals are connected by two Cl atoms and a CH2-py-CH2 group acting, in 3, as a κC (for Ir) : κC,κN (for Rh)-bridging ligand, while, in 4, as a κC (for Rh) : κC,κN (for Ir)-bridging ligand. The structure of the corresponding Rh(III)–Rh(III) complex, [Rh2Cl4(μ-CH2-py-CH2)(PPh3)2] (6), which was incorrectly assigned based on its NMR spectral ..." @default.
• W2023257716 created "2016-06-24" @default.
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• W2023257716 date "1997-09-01" @default.
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• W2023257716 title "Preparation, Characterization, and X-Ray Crystal Structures of<i>μ</i>-2,6-Dimethylpyridine-<i>α</i>,<i>α</i>′-diyl Iridium(III)–Rhodium(III) Complexes and the Structure of [Rh₂Cl₄(<i>μ</i>-CH₂-py-CH₂)(PPh₃)₂](CH₂-py-CH₂= 2,6-Dimethylpyridine-<i>α</i>,<i>α</i>′-diyl) Reinvestigated" @default.
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• W2023257716 doi "https://doi.org/10.1246/bcsj.70.2155" @default.
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