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- W2023257978 abstract "UV polymerization of self-assembled monolayers of a novel carbazolyl-diacetylene (CDS9) chemisorbed on silver films was demonstrated by surface plasmon resonance (SPR) and surface enhanced Raman scattering (SERS) experiments. SPR tests performed during UV exposure permitted one to observe the growth of the absorption coefficient, associated with the formation of the polymeric backbone. The Raman spectra of polymerized monolayers exhibited the bands associated with the CC stretching modes of the conjugated backbone, typical of the blue and red polymeric phases usually present in polydiacetylenes, with a clear predominance of the red form. Moreover, the strong surface enhancement of the Raman band corresponding to the aromatic CC stretching modes suggested that carbazolyl groups arrange nearly perpendicularly to the metal surface. In contrast, the absence of a SERS signal in the region of conjugated C⋮C bond stretchings confirmed a polymerization scheme with conjugated triple bonds nearly parallel to the plane of the metal." @default.
- W2023257978 created "2016-06-24" @default.
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- W2023257978 date "2006-01-01" @default.
- W2023257978 modified "2023-10-18" @default.
- W2023257978 title "UV Polymerization of Self-Assembled Monolayers of a Novel Diacetylene on Silver: A Spectroscopic Analysis by Surface Plasmon Resonance and Surface Enhanced Raman Scattering" @default.
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- W2023257978 doi "https://doi.org/10.1021/la0514157" @default.
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