FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023258219> ?p ?o ?g. }

• W2023258219 endingPage "1802" @default.
• W2023258219 startingPage "1795" @default.
• W2023258219 abstract "Unique (1-aza-2-butenyl)titanium complexes bearing a phosphonium ylide moiety [TiNTbt{C(Me)(PR3)CHC(Me)N(Mes)}Cl] (3−5, Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Mes = 2,4,6-trimethylphenyl) were formed by the nucleophilic attack of PMe3, P(n-Bu)3, and 1,2-bis(dimethylphosphino)ethane (dmpe) toward the corresponding (1-aza-1,3-butadienyl)titanium complex, [TiNTbt{C(Me)CHC(Me)N(Mes)}(μ-Cl)2Li(tmeda)] (2a). The reaction of a lithium β-diketiminate, [Li{N(Tbt)C(Me)CHC(Me)N(Mes)}] (1) with [TiIICl2(dmpe)2] also resulted in the formation of the same complex 5. Density functional theory calculation indicated that the negative charge of the model molecule of 3 was slightly delocalized to the C3N plane. In addition, the calculation of the model molecule of 2a suggested the electrophilicity of 2a at the carbon atom connecting to the titanium atom. Interestingly, the reaction of zirconium and hafnium analogues (2b and 2c) with PMe3 and dmpe did not proceed. In contrast to the cases of phosphine reagents, pyridine which was found to undergo the nucleophilic attack toward the titanium center of 2a gave the pyridine-coordinated titanium-imide [TiNTbt{C(Me)CHC(Me)N(Mes)}Cl(py)] (7)." @default.
• W2023258219 created "2016-06-24" @default.
• W2023258219 creator A5000101907 @default.
• W2023258219 creator A5008562222 @default.
• W2023258219 creator A5089902442 @default.
• W2023258219 date "2007-01-31" @default.
• W2023258219 modified "2023-09-27" @default.
• W2023258219 title "Nucleophilic Attack toward Group 4 Metal Complexes Bearing Reactive 1-Aza-1,3-butadienyl and Imido Moieties" @default.
• W2023258219 cites W1969958859 @default.
• W2023258219 cites W1972244400 @default.
• W2023258219 cites W1975848173 @default.
• W2023258219 cites W1978671612 @default.
• W2023258219 cites W1981490301 @default.
• W2023258219 cites W1983755754 @default.
• W2023258219 cites W1984634720 @default.
• W2023258219 cites W2002362791 @default.
• W2023258219 cites W2002848990 @default.
• W2023258219 cites W2004965020 @default.
• W2023258219 cites W2006170491 @default.
• W2023258219 cites W2011106344 @default.
• W2023258219 cites W2023478234 @default.
• W2023258219 cites W2044556974 @default.
• W2023258219 cites W2051768367 @default.
• W2023258219 cites W2072778583 @default.
• W2023258219 cites W2078470879 @default.
• W2023258219 cites W2079262904 @default.
• W2023258219 cites W2142539606 @default.
• W2023258219 cites W2152223959 @default.
• W2023258219 cites W2346286131 @default.
• W2023258219 cites W2949709605 @default.
• W2023258219 doi "https://doi.org/10.1021/ic0620844" @default.
• W2023258219 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17263525" @default.
• W2023258219 hasPublicationYear "2007" @default.
• W2023258219 type Work @default.
• W2023258219 sameAs 2023258219 @default.
• W2023258219 citedByCount "15" @default.
• W2023258219 countsByYear W20232582192012 @default.
• W2023258219 countsByYear W20232582192016 @default.
• W2023258219 countsByYear W20232582192017 @default.
• W2023258219 countsByYear W20232582192019 @default.
• W2023258219 countsByYear W20232582192020 @default.
• W2023258219 countsByYear W20232582192021 @default.
• W2023258219 countsByYear W20232582192023 @default.
• W2023258219 crossrefType "journal-article" @default.
• W2023258219 hasAuthorship W2023258219A5000101907 @default.
• W2023258219 hasAuthorship W2023258219A5008562222 @default.
• W2023258219 hasAuthorship W2023258219A5089902442 @default.
• W2023258219 hasConcept C145148216 @default.
• W2023258219 hasConcept C155647269 @default.
• W2023258219 hasConcept C161790260 @default.
• W2023258219 hasConcept C178790620 @default.
• W2023258219 hasConcept C178907741 @default.
• W2023258219 hasConcept C185592680 @default.
• W2023258219 hasConcept C188027245 @default.
• W2023258219 hasConcept C2776568683 @default.
• W2023258219 hasConcept C2777000832 @default.
• W2023258219 hasConcept C2777604212 @default.
• W2023258219 hasConcept C2777716191 @default.
• W2023258219 hasConcept C2779167645 @default.
• W2023258219 hasConcept C2779485729 @default.
• W2023258219 hasConcept C2780707935 @default.
• W2023258219 hasConcept C30095370 @default.
• W2023258219 hasConcept C32909587 @default.
• W2023258219 hasConcept C50027330 @default.
• W2023258219 hasConcept C70050531 @default.
• W2023258219 hasConcept C71240020 @default.
• W2023258219 hasConceptScore W2023258219C145148216 @default.
• W2023258219 hasConceptScore W2023258219C155647269 @default.
• W2023258219 hasConceptScore W2023258219C161790260 @default.
• W2023258219 hasConceptScore W2023258219C178790620 @default.
• W2023258219 hasConceptScore W2023258219C178907741 @default.
• W2023258219 hasConceptScore W2023258219C185592680 @default.
• W2023258219 hasConceptScore W2023258219C188027245 @default.
• W2023258219 hasConceptScore W2023258219C2776568683 @default.
• W2023258219 hasConceptScore W2023258219C2777000832 @default.
• W2023258219 hasConceptScore W2023258219C2777604212 @default.
• W2023258219 hasConceptScore W2023258219C2777716191 @default.
• W2023258219 hasConceptScore W2023258219C2779167645 @default.
• W2023258219 hasConceptScore W2023258219C2779485729 @default.
• W2023258219 hasConceptScore W2023258219C2780707935 @default.
• W2023258219 hasConceptScore W2023258219C30095370 @default.
• W2023258219 hasConceptScore W2023258219C32909587 @default.
• W2023258219 hasConceptScore W2023258219C50027330 @default.
• W2023258219 hasConceptScore W2023258219C70050531 @default.
• W2023258219 hasConceptScore W2023258219C71240020 @default.
• W2023258219 hasIssue "5" @default.
• W2023258219 hasLocation W20232582191 @default.
• W2023258219 hasLocation W20232582192 @default.
• W2023258219 hasOpenAccess W2023258219 @default.
• W2023258219 hasPrimaryLocation W20232582191 @default.
• W2023258219 hasRelatedWork W2008650002 @default.
• W2023258219 hasRelatedWork W2020632745 @default.
• W2023258219 hasRelatedWork W2072532915 @default.
• W2023258219 hasRelatedWork W2073540073 @default.
• W2023258219 hasRelatedWork W2144183235 @default.
• W2023258219 hasRelatedWork W2317293357 @default.
• W2023258219 hasRelatedWork W2510244486 @default.
• W2023258219 hasRelatedWork W3128444037 @default.

• next