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- W2023258359 abstract "The order-disorder transition temperatures of the polysaccharides succinoglycan and xanthan are strongly influenced by the salts present in solution. High concentrations of anions such as bromide or thiocyanate lower the transition temperature, thus decreasing the stability of the polymer and increasing its susceptibility to acid catalysed degradation. Salts such as sulphate and phosphate raise the transition temperature but can cause precipitation, and result in the incompatibility of the polymers with certain brines. The effects are in line with the Hofmeister or lyotropic series. The two polysaccharides seem to fit into a spectrum including other biopolymers such as some proteins, although not DNA even though its behaviour is qualitatively similar. The effects arise from the interaction of the salts, primarily the anions, with the solvent water. The hydropholic nature of carbohydrates enables them to structure the solvent to a higher temperature than proteins. The importance of the effect of the polymer on the solvent in considering structure-property relationships cannot the overstressed." @default.
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- W2023258359 title "Influence of anions on the properties of microbial polysaccharides in solution" @default.
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- W2023258359 doi "https://doi.org/10.1016/0141-8130(86)90055-3" @default.
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