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- W2023261079 abstract "The term “structural non-rigidity” is proposed for the measure of the fluctuational flexibility, related to the motion of atoms around the equilibrium position. In the physical sense, this is the relative volume of the states attainable by the molecule at a given temperature, in configurational space. Calculations have been carried out for molecules of various lengths and types, containing double bonds in the main chain: short 4–7 unit chains with two mutually dependent angles of internal rotation, 12- and 17-unit chains of oligomers and the polymers, 1,4-cis- and 1,4-trans-polybutadine, poly-cis- and poly-trans-propenylene and polymethylene. Structural non-rigidity is increased with increase in double bond content of the molecule and also with temperature and depends on the type of bond and molecular length. The values characterizing the structural non-rigidity correlate with the melting points of the oligomers considered and their retention in gas-liquid chromatography." @default.
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- W2023261079 date "1984-01-01" @default.
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- W2023261079 title "The study of structural non-rigidity of molecules with double bonds in the main chain" @default.
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- W2023261079 doi "https://doi.org/10.1016/0032-3950(84)90457-x" @default.
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