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- W2023261716 endingPage "947" @default.
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- W2023261716 abstract "Two POM-pillared 3D porous compounds, [CuICuII(CuIIfcz)2(H2O)5(PMoVI10MoV2O40)]·6H2O (1) and [CuI2(CuIIfcz)2(H2O)2(PMoVI8VV3VIV3O42)]·6H2O (2) (Hfcz = fluconazole, (1-(2,4-difluorophenyl)-1,1-bis[(1H-1,2,4-triazol-1-yl)methyl]benzyl alcohol) have been constructed based on different polyanions, (Cufcz)22+ macrocations and copper cations by the hydrothermal method. The (Cufcz)22+ macrocations link Cu cations to generate a 2D wavelike cationic sheet. Then the POM anions act as pillars to the cationic sheet to form different POM-pillared 3D frameworks. In compound 1, the polyanion exhibits a rare coordination mode and acts as a penta-dentate ligand, which acts as to pillars to the cationic sheet to form an unprecedented 3D (3,4,5,6)-connected open framework with (3·6·7)(32·6·73)(33·4·62·73·8)(34·42·62·76·8)(32·62·76·84·10) topology. In compound 2, polyanions covalently link cationic sheets to extend to an unusual 3D (3,4,6)-connected framework with the (52·6)(52·62·7·9)(54·64·74·93) topology. To the best of our knowledge, it is the first time that POM-pillared 3D metal–organic frameworks have been realized by combining POMs with deliberately designed macrocations and transition-metal ions, using a rational approach for synthesis of POM-based open metal–organic frameworks. In addition, the electrochemical behaviors of compounds 1 and 2 have been investigated." @default.
- W2023261716 created "2016-06-24" @default.
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- W2023261716 date "2009-01-01" @default.
- W2023261716 modified "2023-10-11" @default.
- W2023261716 title "Combination of POMs and deliberately designed macrocations: a rational approach for synthesis of POM-pillared metal–organic framework" @default.
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- W2023261716 doi "https://doi.org/10.1039/b810287b" @default.
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