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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023262016> ?p ?o ?g. }

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• W2023262016 abstract "Chiral allenes are readily accessed in a single pot operation in the reaction of terminal alkynes, aldehydes, chiral secondary amines, and zinc halides in good yields (up to 77% yield) and excellent enantioselectivities (up to 99% ee) in toluene at 120 °C. The reaction proceeds through initial formation of chiral propargylamine intermediates with creation of a new stereogenic center and subsequent chirality transfer via an intramolecular hydride shift to produce chiral allenes with high enantiomeric purities." @default.
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• W2023262016 date "2012-05-15" @default.
• W2023262016 modified "2023-10-15" @default.
• W2023262016 title "Highly Enantioselective Synthesis of Chiral Allenes by Sequential Creation of Stereogenic Center and Chirality Transfer in a Single Pot Operation" @default.
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• W2023262016 doi "https://doi.org/10.1021/ol300717e" @default.
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