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- W2023262243 abstract "Abstract Excess enthalpy data for two binary systems, acetone(1) + n-propanol(2) and acetone(1) + n-butanol(2), were measured with a low-temperature Calvet microcalorimeter at ambient pressure and temperatures of 30 and 35°C. Based on the association solution theory, a temperature-dependent association model (TDA model) was established to describe the excess enthalpy, HE, for the ketone-alcohol systems. For a particular system, the system-dependent parameters, A and B, are related to HE by The relationship between the association heat difference, ΔH, and temperature is expressed as where only three parameters, A, B and ΔH', are needed. By interpolating the HE data of two temperatures, the HE data for the other temperatures can be predicted. The agreement between calculated and experimental data is satisfactory. The results correlated by the TDA model were compared with those by the QCS and Wilson models." @default.
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- W2023262243 date "1990-11-01" @default.
- W2023262243 modified "2023-09-27" @default.
- W2023262243 title "Excess enthalpies for ketone-alcohol systems" @default.
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- W2023262243 doi "https://doi.org/10.1016/0040-6031(90)80158-u" @default.
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