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- W2023262505 abstract "1. Most of the cobalt (III) complex ions of bisethylenediamine series, [Co en2X2](3−2n)+ or [Co en2Y](3−m)+ are reduced irreversibly in two steps at the dropping mercury electrode. The first diffusion current corresponds to the reduction, Co(III)→Co(II) and the second to the reduction, Co(II)→Co(0). The second step always exhibits the maximum wave. 2. The polarographic stability of [Co en2X2] type complexes increases in the following order of the ligands; Br^-, Cl^-<NCS^-<NO_2^-<NH_3<OH_2<CN^- (Supporting electrolyte; 0.5F K2SO4) Similarly, the order of the stability of [Co en2Y] type complexes is as follows; leuc^-<ox^2-<gly^-<SO_3^2-<CO_3^2-<en (Supporting electrolyte; 0.5F K2SO4) These orders are independent of the kind of supporting electrolyte such as potassium chloride or potassium sulfate. The orders of the polarographic stability did not agree with that of the spectrochemical series. 3. In perchloric acid the well-defined wave of steep slope was obtained for diaquo-bisethylenediaminecobalt (III) ion, [Co en2(OH2)2]3+, while the ion gave a modified wave in the neutral solution of 0.1F potassium chloride and of 0.5F potassium sulfate. This phenomena was explained as being due to the inhibition of the dissociation and polymerization of the complex in the presence of an overwhelming hydrogen ion. A similar behavior was observed in the aquo-ammine cobalt (III) complexes." @default.
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- W2023262505 date "1959-02-01" @default.
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- W2023262505 title "Polarographic Studies of Metallic Complexes. IV. Bisethylenediamine Series of Cobalt (III) Complexes" @default.
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- W2023262505 doi "https://doi.org/10.1246/bcsj.32.150" @default.
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