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- W2023264534 abstract "Salts of the violurate anion with the alkali and alkaline earth metals, the d10 ions Zn2+ and Cd2+, Mn2+, Pb2+, Ag+ and the lanthanides show a variety of spectacular colours in the solid state. The metal ions have no intrinsic absorption in the visible region (apart from the weak spin-forbidden bands of Mn2+) and do not normally show charge-transfer absorption. The colours are ascribed to the n→π* transition of the violurate anion. As confirmation of this assignment the visible absorption of the K+ salt is shown to be polarized perpendicular to the plane of the violurate anion. Low temperature (∼20 K) absorption spectra of the Na+, K+ and Rb+ salts are reported." @default.
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- W2023264534 date "1991-01-01" @default.
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- W2023264534 title "The colours of simple salts of the violurate anion" @default.
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- W2023264534 doi "https://doi.org/10.1016/0584-8539(91)80248-h" @default.
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