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- W2023265179 abstract "Metalation of the cyanophenyl mono α-substituted TPA ligand by ferrous chloride affords a stable neutral compound with spectroscopic properties in solution (molecular conductivity, UV-visible and paramagnetic 1H NMR) indicating that the ligand coordinates in the tetradentate mode providing a distorted octahedral geometry around the metal. In the solid state however, the tripod acts as a tridentate ligand, and crystal structure analysis reveals a square pyramidal geometry around the metal. The substituted pyridyl arm is the dangling one, and the cyanide group seems to interact with the metal center of a neighboring molecule. Increasing the ionic strength of a solution of the compound leads to dissociation of the chloride ions from the metal, affording the bis (μ-chloro) diferrous dication, the structure of which is also reported." @default.
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- W2023265179 date "2005-01-01" @default.
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- W2023265179 title "Square pyramidal geometry around the metal and tridentate coordination mode of the tripod in the [6-(3′-cyanophenyl)-2-pyridylmethyl]bis(2-pyridylmethyl)amine FeCl2 complex: a solid state effect" @default.
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- W2023265179 doi "https://doi.org/10.1039/b512108f" @default.
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