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• W2023267738 abstract "For the system Ar + OH electronic adiabatic as well as non-adiabatic vibrational relaxation mechanisms have been studied on the basis of the classical trajectory and the surface-hopping trajectory method, respectively, using simple model potentials for the two lowest electronic states. The collision processes are discussed in detail, especially regarding the influence of the initial rotational angular momentum of the OH molecule which greatly enhances the vibrational deactivation cross sections. Furthermore, thermal rate constants are calculated and compared to recent results from transition state theory; considerable disagreement is found for both mechanisms." @default.
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• W2023267738 date "1986-06-01" @default.
• W2023267738 modified "2023-10-17" @default.
• W2023267738 title "Theoretical investigation of the vibrational relaxation process Ar + OH(ν = 1) → Ar + OH(ν = 0)" @default.
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• W2023267738 doi "https://doi.org/10.1016/0301-0104(86)80052-0" @default.
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