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- W2023272805 abstract "We report on studies of ion-induced nucleation in a corona discharge taking place in an atmosphere containing SO2, NH3, and H2O at standard temperature and pressure. Positive ions such as H3O+(H2O)n, NH4+(H2O)n, and H+(H2SO4)(H2O)n and negative ions such as HSO5−(H2O)n, SO4−(H2O)n, HSO4−(H2O)n and NO3−(H2O)n have been recorded. Large values of n (>100) were observed and the experiment indicates the existence of even larger water clusters. In contrast, only clusters with a maximum of 2 sulfuric acid molecules were observed. Fragmentation studies also revealed that the negative ion HSO5−, which has been observed in many studies, in our experiments is contaminated by O2−(HNO3)(H2O) ions, and this may also have been the case in other experiments. Finally an ion with m/z = 232 (where m is the cluster mass in amu and z is the charge state), capable of attaching H2O-molecules was observed and studied by fragmentation." @default.
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- W2023272805 date "2013-05-01" @default.
- W2023272805 modified "2023-10-17" @default.
- W2023272805 title "Experimental studies of the formation of cluster ions formed by corona discharge in an atmosphere containing SO2, NH3, and H2O" @default.
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- W2023272805 doi "https://doi.org/10.1016/j.ijms.2013.03.001" @default.
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