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- W2023274075 abstract "The new molecule based on 12-molybdophosphate acid and dibenzo-18-crown-6, [(H3O)(C20H24O6)]2[HPMo12O40]·C20H24O6·3MeCN·H2O 1, was synthesized in acetonitrile and characterized by elemental analyses, IR, 1H NMR, electrospray mass spectra and single crystal X-ray diffraction, indicating that it contains [(H3O)(dibenzo-18-crown-6)]+ cations, where oxonium ions are out of the planes defined by crown ether oxygen atoms, and disordered PMo12O403− anions with α-Keggin structure where the crystal has high lattice energy so that it is difficult to dissolve it. The crystallographic disorder averages Mo–Mo distances and Mo–Ob/c–Mo angles between the M3 triplets and within the M3 triplet. The interactions between crown ether molecules and oxonium ions are hydrogen-bonding with the O(crown ether)–OH3+ distances of 2.510(10)–2.783(7) Å. The interactions between [(H3O)(dibenzo-18-crown-6)]+ cations and PMo12O403− anions are dominantly electrostatic. The electrical conductivity is <10−7 S.cm−1." @default.
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- W2023274075 date "2002-02-01" @default.
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- W2023274075 title "A molecule based on polyoxometalate acid and crown ether: synthesis and characterization of [(H3O)(C20H24O6)]2[HPMo12O40]·C20H24O6·3MeCN·H2O (C20H24O6=dibenzo-18-crown-6)" @default.
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- W2023274075 doi "https://doi.org/10.1016/s0022-2860(01)00756-6" @default.
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