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• W2023275711 endingPage "837" @default.
• W2023275711 startingPage "827" @default.
• W2023275711 abstract "We describe the synthesis and dioxygen reactivity of diiron(II) tetracarboxylate complexes [Fe(2)(mu-O(2)CAr(Tol))(2)(O(2)CAr(Tol))(2)(N,N-Me(2)en)(2)] (2) and [Fe(2)(mu-O(2)CAr(Tol))(2)(O(2)CAr(Tol))(2)(N,N-Bn(2)en)(2)] (6), where Ar(Tol)CO(2)(-) = 2,6-di(p-tolyl)benzoate. These complexes were prepared as models for the diiron(II) center in the hydroxylase component of soluble methane monooxygenase (MMOH). Compound 6 reacts with dioxygen to afford PhCHO in approximately 60(5)% yield, following oxidative N-dealkylation of the pendant benzyl group on the diamine ligand. The diiron(III) complex [Fe(2)(mu-OH)(2)(mu-O(2)CAr(Tol))(O(2)CAr(Tol))(3)(N-Bnen)(N,N-Bn(2)en)] (8) was isolated from the reaction mixture. The 4.2 K Mössbauer spectrum of 8 displays a single quadrupole doublet with parameters delta = 0.48(2) mm s(-1) and Delta E(Q) = 0.61(2) mm s(-1). The [Fe(2)(mu-OH)(2)(mu-O(2)CR)](3+) core structure in 8 matches that of the fully oxidized form of MMOH. The conversion of 6 to 8 closely parallels the chemistry of MMOH in which an O(2)-derived oxygen atom is inserted into the C-H bond of methane. Several reaction pathways are considered to account for this novel chemical transformation, and these are compared with mechanistic frameworks previously developed for related cytochrome P450 and copper(I) dioxygen chemistry." @default.
• W2023275711 created "2016-06-24" @default.
• W2023275711 creator A5032470300 @default.
• W2023275711 creator A5034625027 @default.
• W2023275711 date "2002-01-31" @default.
• W2023275711 modified "2023-10-17" @default.
• W2023275711 title "Synthetic Analogue of the {Fe₂(μ-OH)₂(μ-O₂CR)}³⁺ Core of Soluble Methane Monooxygenase Hydroxylase via Synthesis and Dioxygen Reactivity of Carboxylate-Bridged Diiron(II) Complexes" @default.
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• W2023275711 doi "https://doi.org/10.1021/ic011008s" @default.
• W2023275711 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11849083" @default.
• W2023275711 hasPublicationYear "2002" @default.
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