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- W2023277457 abstract "Abstract The reaction of Se, I 2 and WCl 6 in the molar ratio 12:1:2 in a sealed evacuated ampoule at 423 K yields (Se 6 I + ) n · n (WCl 6 − ) in quantitative yield as black, moisture sensitive crystals with a bronze luster. The compound crystallizes triclinic (space group P [unk]) with the lattice constants a = 670.1(3) pm, b = 741.7(5) pm, c = 803.5(5)pm, α = 92.18(5)°, β = 97.71(4)°, γ = 95.48(4)°. The structure was refined to R W ( F 2 ) = 9.2% based on 2248 unique reflections and r (| F |) = 3.7% based on 1912 reflections with | F | > 4 σ ( F ). The one-dimensional polymeric cation (Se 6 I + ) n is built of Se 6 rings in the chair conformation which are connected by iodine atoms bound to the Se 6 rings in the 1,4 positions and forming linear bridges. The WCl 6 − anions form slightly distorted octahedra. The structure is compared with that of (Se 6 I)MF 6 (M = As, Sb) with a nearly isostructural polycation." @default.
- W2023277457 created "2016-06-24" @default.
- W2023277457 date "1995-04-01" @default.
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- W2023277457 title "A polymeric (iodo)selenium cation in the structure of (Se<sub>6</sub>I)WCl<sub>6</sub>" @default.
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- W2023277457 doi "https://doi.org/10.1524/zkri.1995.210.4.265" @default.
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