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- W2023282310 abstract "The ion-interaction type of equation which has proven so successful for activity and osmotic coefficents of both pure and mixed electrolytes near room temperature is extended for wide temperature ranges and for the enthalpy and heat capacity. An improved equation is obtained for the dielectric constant of water over a wide range of temperature and density; it is used to calculate the Debye-Hueckel parameters to 350/sup 0/C for enthalpy and heat capacity as well as for osmotic and activity coefficients. These equations are applied to the extensive array of thermodynamic data for aqueous sodium chloride from 0 to 300/sup 0/C. Good agreement is obtained and the equations thus provide a convenient analytical representation of the thermodynamic properties of NaCl(aq). Also the results indicate that at 300/sup 0/C sodium chloride is still a strong electrolyte with little tendency toward the formation of ion pairs." @default.
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- W2023282310 date "1977-09-01" @default.
- W2023282310 modified "2023-10-18" @default.
- W2023282310 title "Thermodynamics of electrolytes. 8. High-temperature properties, including enthalpy and heat capacity, with application to sodium chloride" @default.
- W2023282310 doi "https://doi.org/10.1021/j100534a007" @default.
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