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- W2023286073 abstract "Summary Ten lactating dairy cows were given 1-C 14 and 2-C 14 acetate and 1-C 14 , 2-C 14 , and 3-C 14 butyrate by intravenous injection in a series of separate investigations. Butyric, caproic, and caprylic acids were isolated from the milk fat produced at 3 and 10 hr after injection and were degraded to determine their intramolecular C 14 labeling patterns. Our results provide additional proof that low molecular weight milk fatty acids are synthesized via the successive addition of two carbon units. These condensation reactions appear to be highly organized and give rise to carbon 14 labeling patterns which suggest that the carboxyl carbon of the primary precursor—presumably Acetyl CoA—retains its identity as the carboxyl carbon of the higher milk fatty acids. Thus, carbon chain elongation seems to proceed at the methyl end of the primary precursor and of each successive two carbon homologue. Lastly, we obtained strong evidence that the four carbon skeleton of butyrate may be utilized as such for the synthesis of the lower milk fatty acids. However, it appears that this is a relatively minor pathway of butyrate metabolism—the major pathway being beta oxidation to Acetyl CoA molecules which are, in turn, used for fatty acid synthesis." @default.
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- W2023286073 date "1964-08-01" @default.
- W2023286073 modified "2023-09-29" @default.
- W2023286073 title "In Vivo Synthesis of Certain Low Molecular Weight Milk Fatty Acids" @default.
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- W2023286073 doi "https://doi.org/10.3168/jds.s0022-0302(64)88788-9" @default.
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