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• W2023287796 abstract "Mercury(II) is reduced to mercury(I) upon irradiation (λir = 254 nm) in air-saturated aqueous solution containing ethanol. The quantum yield of this reaction linearly depends on the alcohol concentration. The product of this process is Hg22+, which is photoactive too. Photostationary state with Hg(I)/Hg(II) ratio depending on the alcohol concentration can be reached in this system. Thus, photoassisted catalytic oxidation of alcohol to aldehyde takes place in such a state. Flash photolysis experiments confirmed that the reactions of Hg+ and Hg2+ formed in the primary steps of the photoinduced process are strongly affected by mercury(II), oxygen, and alcohol." @default.
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• W2023287796 date "1999-11-01" @default.
• W2023287796 modified "2023-10-01" @default.
• W2023287796 title "Photoredox chemistry of mercury ions in aqueous ethanol solutions" @default.
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• W2023287796 doi "https://doi.org/10.1016/s1010-6030(99)00168-9" @default.
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