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• W2023288842 abstract "The average orientation and flexibility of the phosphorylcholine group are deduced from deuterium and phosphorus-31 nuclear magnetic resonance measurements of unsonicated phosphatidylcholine bilayers in the liquid crystalline state. The experimental data are consistent with a model in which the polar head group exhibits a restricted flexibility characterized by rapid transitions between two enantiomeric conformations. A completely flexible or a completely rigid head group structure can be excluded. The phosphorylcholine residue is found to be bent at the position of the phosphate group, due to a gauchegauche conformation of the phosphodiester linkage. The choline dipole is aligned parallel to the plane of the membrane, which is in agreement with X-ray and neutron diffraction studies. The average orientation of the phosphorylcholine group is therefore the same as that of the phosphorylethanolamine head group." @default.
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• W2023288842 date "1977-06-01" @default.
• W2023288842 modified "2023-10-01" @default.
• W2023288842 title "Orientation and flexibility of the choline head group in phosphatidylcholine bilayers" @default.
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• W2023288842 doi "https://doi.org/10.1016/0005-2736(77)90188-2" @default.
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