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- W2023293131 abstract "The cluster [Os3(CO)10(MeCN)2] reacts readily with azulene in refluxing cyclohexane to give the oxidative addition product [Os3(μ-H)(μ2-η1-C10H7)(CO)10] 1 which was shown by its X-ray crystal structure to contain the C5 ring of the azulenyl ligand bonded through a single carbon atom at the 1-position. We propose that the compound is zwitterionic, with the 7-membered ring a tropylium cation and the 5-membered ring coordinated as a μ-alkylidene to the metal cluster, which carries a formal negative charge. Thermal loss of one CO ligand leads by further oxidative addition to the known cluster [Os3(μ-H)2(μ3-η1:η1:η1-C10H6)(CO)9] 2." @default.
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- W2023293131 date "2004-06-01" @default.
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- W2023293131 title "A zwitterionic triosmium cluster bearing a metallated azulene ligand coordinated perpendicularly as an alkylidene bridge" @default.
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- W2023293131 doi "https://doi.org/10.1016/j.jorganchem.2004.03.028" @default.
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