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- W2023295486 abstract "The nature of the solvent has a small influence on the position of the longest wavelength absorption band and the oscillator strength (S0→S1 transition) of (BDH)+Cl−. A linear correlation between the molar excitation energy of (BDH)+Cl− and the refractive index functionf(n) = (n2−1) / (2n2+1) proves that dispersion forces are mainly responsible for the position of the longest absorption wavelength. Furthermore, the oscillator strength decreases with a rising value of the mentioned refractive index function. This means that dispersion forces cause a small disturbance of the ideal polymethine state in the first excited singlet state and lead to a decrease in the transition probability." @default.
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- W2023295486 date "1994-10-01" @default.
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- W2023295486 title "Solvent effects on the UV/VIS absorption spectrum of bis-(dimethylamino)-heptamethinium chloride [(BDH)+Cl−]" @default.
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