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- W2023303008 abstract "Binders and plasticizers are key materials that decide the mechanical properties of composite propellants. Hydroxyl-terminated polybutadiene (HTPB) is commonly used as a binder for composite propellants, while polytetrahydrofuran (PTHF) is a useful plasticizer of the HTPB binder. In this study, the dynamic mechanical properties of cured HTPB containing PTHF were investigated, and the network structure of the blend was estimated to obtain useful data for the development of binders and plasticizers. The network density of the HTPB/PTHF blend was reduced by the addition of PTHF; furthermore, the temperature and frequency dependences of the modulus and loss tangent varied. It was inferred that a small amount of the added PTHF was incorporated into the network structure of the cured HTPB. And the PTHF incorporated into the network structure of the cured HTPB probably formed dangling ends in the network, thereby enhancing the mobility of the chain segment of the blends. The dynamic mechanical properties of the blends followed the time-temperature superposition principle, and the properties were estimated accurately by the Williams-Landel-Ferry approach. The apparent activation energy of relaxation of the HTPB/PTHF blends was smaller than that of HTPB alone." @default.
- W2023303008 created "2016-06-24" @default.
- W2023303008 creator A5064614391 @default.
- W2023303008 date "2012-01-01" @default.
- W2023303008 modified "2023-10-18" @default.
- W2023303008 title "Dynamic Mechanical Properties of Hydroxyl-terminated Polybutadiene Containing Polytetrahydrofuran as a Plasticizer" @default.
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- W2023303008 doi "https://doi.org/10.1678/rheology.40.185" @default.
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