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- W2023306871 abstract "Regioselective arylation in the 4-position in pyridines results from 1:1-adduct formation between an aryltriisopropoxytitanium reagent and N-isobutyloxycarbonyl- or an N-silyloxymethyl-3-cyanopyridinium salt after successive DDQ dehydrogenation and cleavage of the 1-substituent. Complete regioselectivity for new CC bond formation in the 4-position results in the adduct formation between aryl- and phenylethynyltri-isopropoxytitanium reagents and pyrimidin-2(1H)-ones; with ethynyltriisopropoxytitanium the new CC bond formation occurs at the 6-position." @default.
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- W2023306871 title "Aryl- and alkynyltri-isopropoxytitanium reagents in regioselective carbon-carbon bond formation in azines" @default.
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