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- W2023307961 abstract "The laser Raman and infrared spectra of Li, Na, K, Rb, Cs bicarbonates and carbonates in H 2 O and D 2 O have been determined at 25 °C. The relative integrated intensities of the Raman bands have been measured for each salt from 0.01 M up to saturation. Changes observed in the carbonate spectrum with concentration have been interpreted in terms of solvation and ion-pairing of the carbonate ion. Based on the vibrational spectrum, there was no evidence for ionic interactions in the bicarbonate solutions. The hydrogen–deuterium exchange on the bicarbonate ion in H 2 O–D 2 O mixtures has been followed using Raman spectroscopy and the concentration quotients for the pertinent reactions have been calculated." @default.
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- W2023307961 date "1973-03-01" @default.
- W2023307961 modified "2023-10-10" @default.
- W2023307961 title "Vibrational Spectroscopic Studies of Aqueous Alkali Metal Bicarbonate and Carbonate Solutions" @default.
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- W2023307961 doi "https://doi.org/10.1139/v73-106" @default.
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