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• W2023320340 abstract "The paper presents a chemo-mechanical model for expansive clays that takes into account the effects of cation content and cation exchange. These factors play a key role in the mechanical behaviour of very active clays, particularly with regard to volumetric behaviour. The model is based on an existing double-structure formulation that distinguishes specifically between microstructure and macrostructure. Chemical effects are defined at the microstructural level, the seat of the basic physico-chemical phenomena affecting highly swelling clays. The microstructural model accounts for changes in both osmotic suction and in cation content. Microstructural strains are considered to be reversible; material irreversibility arises from the interaction between the two structural levels. The formulation is developed for general unsaturated conditions; saturation is considered as a limiting case. The model is successfully applied to the reproduction of experimental behaviour observed in oedometer tests on saturated bentonite subjected to chemo-mechanical loadings, and in hydration tests of unsaturated bentonite performed using different solute concentrations." @default.
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• W2023320340 date "2013-03-01" @default.
• W2023320340 modified "2023-09-27" @default.
• W2023320340 title "A chemo-mechanical constitutive model accounting for cation exchange in expansive clays" @default.
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• W2023320340 doi "https://doi.org/10.1680/geot.sip13.p.012" @default.
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