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- W2023326507 abstract "Abstract Single-crystalline nanorods of β -MnO 2 , α -Mn 2 O 3 and Mn 3 O 4 were successfully synthesized via the heat-treatment of γ -MnOOH nanorods, which were prepared through a hydrothermal method in advance. The calcination process of γ -MnOOH nanorods was studied with the help of Thermogravimetric analysis and X-ray powder diffraction. When the calcinations were conducted in air from 250 to 1050 °C, the precursor γ -MnOOH was first changed to β -MnO 2 , then to α -Mn 2 O 3 and finally to Mn 3 O 4 . When calcined in N 2 atmosphere, γ -MnOOH was directly converted into Mn 3 O 4 at as low as 500 °C. Transmission electron microscopy (TEM) and high-resolution TEM were also used to characterize the products. The obtained manganese oxides maintain the one-dimensional morphology similar to the precursor γ -MnOOH nanorods. Further experiments show that the as-prepared manganese oxide nanorods have catalytic effect on the oxidation and decomposition of the methylene blue (MB) dye with H 2 O 2 ." @default.
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- W2023326507 date "2006-03-01" @default.
- W2023326507 modified "2023-10-18" @default.
- W2023326507 title "Nanorods of manganese oxides: Synthesis, characterization and catalytic application" @default.
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- W2023326507 doi "https://doi.org/10.1016/j.jssc.2005.11.028" @default.
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