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- W2023335786 abstract "Biomimetic oxygen activation on binuclear iron active sites occluded within the voids of mesoporous oxides such as HMS (hexagonal mesoporous silica) is an interesting new field of research. As guests, binuclear iron(III) complexes were chosen. Heptapodate N,N,N′,N′-tetrakis(2-R methyl)-2-hydroxy-1,3-diaminopropane ligands in which R is either a pyridyl or a benzimidazole group allow metal coordination as in methane mono-oxygenase active sites. The physicochemical characterization with SEM, TGA and sorption analysis shows the interactions of the complexes with the support. IR, Raman and diffuse reflectance-UV-Vis-NIR spectroscopy is used to monitor interaction of oxygen (16O2 and 18O2) or peroxides with the supported active sites. The cyclohexane, cyclohexylhydroperoxide and isobutane oxidation is described and the mono- and binuclear mechanisms that are occurring in nucleophilic and electrophilic activation pathways are discussed." @default.
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- W2023335786 date "1998-05-01" @default.
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- W2023335786 title "Alkane oxidation by dinuclear iron complexes in hexagonal mesoporous solids" @default.
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- W2023335786 doi "https://doi.org/10.1016/s1387-1811(98)00132-2" @default.
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