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• W2023336891 abstract "Catalyzed by Rhodococcus erythropolis AJ270, an amidase-containing microbial whole cell catalyst, under very mild conditions, a number of functionalized prochiral malonamides underwent enantioselective desymmetrization reaction to afford high yield of carbamoylacetic acids with moderate to excellent enantioselectivity. The synthetic application has been demonstrated with a multi-gram scale biocatalytic preparation of R-(−)-α-allyl-α-methyl-carbamoylacetic acid and its conversions to varied α,α-disubstituted α-amino acids of the interest of medicinal chemistry." @default.
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• W2023336891 date "2011-08-01" @default.
• W2023336891 modified "2023-10-06" @default.
• W2023336891 title "Microbial whole cell-catalyzed desymmetrization of prochiral malonamides: practical synthesis of enantioenriched functionalized carbamoylacetates and their application in the preparation of unusual α-amino acids" @default.
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• W2023336891 doi "https://doi.org/10.1016/j.tet.2011.05.103" @default.
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