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- W2023337308 abstract "A hydrothermal reaction of a mixture containing iron(II) oxalate dihydrate, phosphorus acid, piperazine, and water at 150 °C for 72 h gave light-yellow cubes of a new hybrid iron oxalate−phosphite, [C4N2H12][FeII4(HPO3)2(C2O4)3], I. The structure, formed by FeO6, HPO3, and oxalate building units, possesses infinite one-dimensional chains of Fe−O−Fe, formed by Fe2O10 dimers. The phosphite units are grafted to these chains, and the oxalate moieties bond with the iron center through in-plane and out-of-plane connectivity forming a three-dimensional structure with intersecting channels. The organic amine molecule occupies the middle of the channels. The connectivity between the phosphite units and the Fe−O−Fe chains resembles the tancoite structure. Magnetic investigations reveal that the iron is present in the +2 oxidation state and orders antiferromagnetically." @default.
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- W2023337308 date "2005-04-30" @default.
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- W2023337308 title "Inorganic−Organic Hybrid Compounds: Synthesis, Structure, and Magnetic Properties of the First Organically Templated Iron Oxalate−Phosphite, [C<sub>4</sub>N<sub>2</sub>H<sub>12</sub>][Fe<sup>II</sup><sub>4</sub>(HPO<sub>3</sub>)<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>], Possessing Infinite Fe−O−Fe Chains" @default.
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