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• W2023339948 abstract "Divalent metal halides react with pyridyloxy-substituted 2,2‘-dioxybiphenyl-cyclotri- and cyclotetraphosphazene ligands to form the complexes, [MLX2] [M = Co or Cu; L = (2,2‘-dioxybiphenyl)tetrakis(2-pyridyloxy)cyclotriphosphazene (L1) or (2,2‘-dioxybiphenyl)tetrakis(4-methyl-2-pyridyloxy)cyclotriphosphazene (L2); X = Cl or Br], [ZnLCl2] [L = bis(2,2‘-dioxybiphenyl)bis(2-pyridyloxy)cyclotriphosphazene (L3) or bis(2,2‘-dioxybiphenyl)bis(4-methyl-2-pyridyloxy)cyclotriphosphazene (L4)], [MLCl2] [M = Cu or Hg; L = tris(2,2‘-dioxybiphenyl)bis(2-pyridyloxy)cyclotetraphosphazene (L5)] and [Cu2LCl4] (L = trans-bis(2,2‘-dioxybiphenyl)tetrakis(2-pyridyloxy)cyclotetraphosphazene (L6)]. Single-crystal X-ray structures show the L2 ligand complexes to have a N3Cl2 five-coordinate, trigonal-bipyramidal donor set with the phosphazene ring and pendant pyridyloxy nitrogens binding to the metal ions. The coordinated L2 ligand in the complex, [CoL2Cl2], slowly hydrolyses in acetonitrile with the loss of a pyridine pendant arm to form a dimetallic species, which has been characterized by crystallography as [{CoL2aCl}]2·4MeCN (L2a = [N3P3(biph)(OPy)3(O)]-, biph = 2,2‘-dioxybiphenyl, OPy = 2-oxopyridine). The ligands, L3, L4, L5, and L6, bind to the metal halides via gem-substituted pyridyloxy nitrogens only. The resulting rigid eight-membered chelate rings all have distorted boat conformations, which force distorted-tetrahedral N2Cl2 coordination environments onto the metal ions. The spectroscopic (ESR and electronic) and magnetic properties of the complexes are reported." @default.
• W2023339948 created "2016-06-24" @default.
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• W2023339948 date "2007-10-20" @default.
• W2023339948 modified "2023-09-23" @default.
• W2023339948 title "Conformationally Rigid Chelate Rings in Metal Complexes of Pyridyloxy-Substituted 2,2‘-Dioxybiphenyl-Cyclotetra- and Cyclotriphosphazene Platforms" @default.
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• W2023339948 doi "https://doi.org/10.1021/ic701241v" @default.
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