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- W2023341571 abstract "Abstract The pore-size dependence of liquid diffusivity in mesopores has been under much debate as two opposite views have been developed. It is especially meaningful in dye-sensitized solar cells (DSSCs) because the ion diffusivity in electrolyte is closely related to the cell performance. Using DC polarization measurements, pore-size dependence of ion diffusivity in DSSCs was investigated based on TiO 2 thin films with variable average pore diameters, which were prepared from TiCl 4 post-treatments. The respective valid ranges of pore-size dependent and independent regimes were obtained from the trend of normalized diffusivities, which were separated by the transition point located at 5–7 nm in between. In addition, we showed that DSSC fabrication processes, e.g., dye loading, TiCl 4 post-treatment will not trigger the transition of diffusion behaviors. Furthermore, the unexpected drop of diffusivity after one TiCl 4 treatment is attributed to the involvement of surface diffusion in untreated TiO 2 matrix." @default.
- W2023341571 created "2016-06-24" @default.
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- W2023341571 date "2013-07-01" @default.
- W2023341571 modified "2023-10-14" @default.
- W2023341571 title "Transition of pore-size dependence of ion diffusivity in dye-sensitized solar cells" @default.
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- W2023341571 doi "https://doi.org/10.1016/j.electacta.2013.03.166" @default.
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