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• W2023343644 abstract "Supported hybrid catalysts using metallocenes and a nickel diimine catalyst were synthesized and used for ethylene slurry polymerization and ethylene/1-hexene copolymerization. Two types of metallocenes, together with a nickel diimine catalyst were supported onto SiO2 through chemical bonding, and a borate compound was physisorbed for the activation of the catalysts. These supported hybrid catalysts had high catalyst activities and made free-flowing polymer particles. The chemical composition distribution, molecular weight averages and distributions of resultant polymers were controlled by catalyst structure and polymerization conditions such as reaction temperature and the use of α-olefin. According to GPC-IR, 13C NMR and CEF characterization results of some polymers, more 1-hexene was incorporated in the high molecular weight region, short chain branches were generated by the chain walking mechanism in low molecular weight region. The morphologies of the resulting particles were investigated by SEM." @default.
• W2023343644 created "2016-06-24" @default.
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• W2023343644 date "2010-10-01" @default.
• W2023343644 modified "2023-10-16" @default.
• W2023343644 title "Supported hybrid early and late transition metal catalysts for the synthesis of polyethylene with tailored molecular weight and chemical composition distributions" @default.
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• W2023343644 doi "https://doi.org/10.1016/j.polymer.2010.08.030" @default.
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