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- W2023344572 abstract "A novel group transfer polymerization via hetero-Diels-Alder reaction is described. When 1-trimethylsiloxybenzocyclobutene (1) was treated with a catalytic amount of p-anisaldehyde (4-methoxybenzaldehyde) and TASF (tris(dimethylamino)sulfonium difluorotrimethylsilanide) at room temperature for 0.5 h, poly[1,2-phenylene-1-(trimethylsiloxy)ethylene] was obtained quantitatively. The number-average molecular weight of the polymer was M̄n = 2000 and the molecular weight distribution was narrow (ratio of weight-to number-average molecular weights M̄w/M̄n = 1.18). Structural characteristics suggested a polymerization mechanism involving isomerization of 1 to o-quinodimethane and successive hetero-Diels-Alder reaction leading to poly[1,2-phenylene-1-trimethylsiloxy ethylene]. The living-like nature of the polymerization was supported by a monomer addition experiment in which the molecular weight increased according to the increase of the added monomer." @default.
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- W2023344572 date "1996-03-01" @default.
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- W2023344572 title "A novel group transfer polymerization of 1-trimethylsiloxy-benzocyclobutene via hetero Diels-Alder reaction" @default.
- W2023344572 doi "https://doi.org/10.1002/marc.1996.030170302" @default.
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