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- W2023345095 abstract "The formation entropy of Schottky defects (vacancies) is calculated from the entropy of fusion and the concentration xL = 0.125 of vacancies within the melt at melting point Tm. The formation of vacancies is connected with a decrease of the vibrational frequency of those lattice forming particles (atoms, ions, molecules) being neighbours of the vacancies. Theoretical values of the vacancy concentrations xs agree with those xs obtained with the help of experimentally determined free formation enthalpies of the defects. Die Bildungsentropie der Schottky-Defekte (Leerstellen) wird aus der Schmelzentropie und der Leerstellenkonzentration xL = 0.125 in der Schmelze am Schmelzpunkt Tm berechnet. Die Bildung der Leerstellen ist mit einem Abfall der Schwingungsfrequenz der Gitterbausteine (Atome, Ionen, Moleküle) in der Nachbarschaft der Leerstellen verbunden. Theoretische Werte der Leerstellenkonzentration xs stimmen gut mit jenen überein, die mit Hilfe experimentell ermittelter freier Bildungsenthalpie der Defekte bestimmt worden sind." @default.
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- W2023345095 title "Estimation of point defect parameters of solids on the basis of a defect formation model of melting (III). Formation entropy and concentration of schottky defects (vacancies)" @default.
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- W2023345095 doi "https://doi.org/10.1002/crat.2170240511" @default.
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