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• W2023347984 abstract "Magnesium cyclopropylidene was generated from 1-chlorocyclopropyl phenyl sulfoxide with i-PrMgCl in THF at −78 °C in high yield by a sulfoxide–magnesium exchange reaction. The generated magnesium cyclopropylidene was found to be reactive with N-lithio arylamines to give α-amino-substituted cyclopropylmagnesiums. The reaction of the α-amino-substituted cyclopropylmagnesiums with several electrophiles was examined and a new method for a synthesis of cyclopropane amino acid derivatives was realized." @default.
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• W2023347984 date "2006-04-01" @default.
• W2023347984 modified "2023-10-11" @default.
• W2023347984 title "Reaction of magnesium cyclopropylidene with N-lithio arylamines: a method for generation of α-amino-substituted cyclopropylmagnesiums and a study for their reactivity with electrophiles" @default.
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• W2023347984 doi "https://doi.org/10.1016/j.tet.2006.01.080" @default.
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