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- W2023348242 abstract "Application of the (S)-(+)-N-(3,5-dinitrobenzoyl)-1-phenylethylamine 1 and (S)-(+)-N-(3,5-dinitrobenzoyl)-1-(1-naphthyl)ethylamine 2 as chiral NMR shift agents for a variety of phospholene derivatives is described. 1H and 31P NMR spectra recorded in the presence of Kagan's amides 1 or 2 show well resolved signals of vinylic protons as well as 31P signals and allow effective measurement of the enantiomeric excesses. The experimental rule for determination of the absolute configuration at P is also proposed." @default.
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- W2023348242 date "2003-06-01" @default.
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- W2023348242 title "The classical Kagan's amides are still practical NMR chiral shift reagents: determination of enantiomeric purity of P-chirogenic phospholene oxides" @default.
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