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• W2023348660 endingPage "36" @default.
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• W2023348660 abstract "The tris(indazol-1-yl)borate complexes PdMe3{(ind)3BH} (2a′) and PtMe3{(ind)3BH} · 0.5CH2Cl2 (2b′) are obtained on reaction of PdMe2(tmeda) (tmeda=N,N,N′,N′-tetramethylethylenediamine) or [PtMe2(SEt2)]2 with Tl[(ind)3BH], respectively, followed by addition of iodomethane. X-ray structural studies of these complexes, together with theoretical calculation at the SCF level of geometries for these complexes and [MMe3{(pz)3CH}]+ using [(H2CN–NH)3BH]− as a model for [(ind)3BH]− and (H2CN–NH)3CH as a model for tris(pyrazol-1-yl)methane, respectively, are reported. The theoretical studies model the trends in coordination geometry determined crystallographically on going from Pd to Pt and from [(ind)3BH]− to (pz)3CH as ligands, in particular M–N is longer and the ′N⋯N′ ‘bite’ is larger for palladium than platinum complexes, and the N⋯N′ ‘bite’ is larger for the borate complexes. Calculations at the SCF level indicate that [(pz)3BH]− has a larger intrinsic ‘bite’ than isoelectronic (pz)3CH." @default.
• W2023348660 created "2016-06-24" @default.
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• W2023348660 date "1999-04-01" @default.
• W2023348660 modified "2023-10-11" @default.
• W2023348660 title "Coordination geometries for palladium and platinum: theoretical studies and the synthesis and structure of tris(indazol-1-yl)borate complexes MMe3{(ind)3BH}" @default.
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• W2023348660 doi "https://doi.org/10.1016/s0020-1693(98)00402-2" @default.
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